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How to calculate a trimolecular reaction with mesmer

jingxin
2024-03-18
2024-03-18
  • jingxin

    jingxin - 2024-03-18

    Dear all,
    I'm trying to run a trimolecular reaction by MESMER. The examples given in the MESMER tutorial are all bimolecular reactions. Can MESMER calculate trimolecular reactions?

    If so, how should I set up the input file.

    The reaction schematic I'm trying to set up is in attachment ( fig.jpg ). The three reactant molecules are marked in yellow.

    Looking forward to your reply, thanks!

    Regards, jinigxin

     
  • struanr

    struanr - 2024-03-18

    Dear jinigxin,

    Thank-you for your message.

    I believe it may be possible to model your system but how this is done depends on the type of species represented by IM2, that is is it a true stationary point on the surface or an inflexion? To put it another way, is there a barrier between IM1 and IM2? If you can share some details of your system with me, I might be able to help a little more.

    With regards, Struan

     

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