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GPG Keychain Access doesn't use the latest MacGPGME framework version (1.1),
and thus expects gpg to be located in /usr/local/bin/. Once it will use
MacGPGME 1.1 framework, users will be able to use a different location for gpg.
As you mention it, GPG Keychain Access should check for gpg presence at
startup, and warn user when it can't find it. (I'm not the maintainer)